Are compliance constants ill-defined descriptors for weak interactions?
نویسندگان
چکیده
منابع مشابه
III-defined concepts in chemistry: rigid force constants vs. compliance constants as bond strength descriptors for the triple bond in diboryne
In a recent publication, the interpretation of Braunschweig's diboryne NHC-BB-NHC as a true triple bond is questioned. The analysis by Köppe and Schnöckel is based, inter alia, on the calculation of rigid coupling force constants. Nevertheless, since it is known for a long time that the use of rigid force constants as bond strength descriptors is by no means straightforward, we recomputed the r...
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ژورنال
عنوان ژورنال: RSC Advances
سال: 2013
ISSN: 2046-2069
DOI: 10.1039/c3ra22866e